Which of the following will not undergo Hell-Volhard-Zelinsky reaction

Which Of The Following Will Not Undergo Hellvolhardzelinsky Reaction Chemistry Question

Which of the following will not undergo Hell-Volhard-Zelinsky reaction

Options

(a) Acetic acid
(b) Formic acid
(c) Propionic acid
(d) 2-Methyl propionic acid

Correct Answer:

Formic acid

Explanation:

Carboxylic acid which contain α – hydrogen atom reacts with chlorine or bromine in presence of red phosphorus to give α – chloro or α – bromo acids. This reaction is called H.V.Z (Hell Volhard Zelinsky ) reaction. CH₃COOH → CCl₃COOH(trichloroacetic acid). CH₃CH₂COOH → CH₃CBr₂COOH (α,α-dibromopropionic acid) Due to absence of α – H atom HCOOH does not undergo HVZ reaction.

Related Questions:

  1. Which azide is explosive
  2. Acidity of diprotic acids in aqueous solutions increases in the order
  3. In an exothermic reaction(reversible) which of the following has positive value
  4. In which of the following acid – base titration,pH is greater than 8
  5. Which one of the following species does not exist under normal conditions?

Topics: Aldehydes Ketones and Carboxylic Acid (89)
Subject: Chemistry (2512)

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