When acetone reacts with bleaching powder, the compound formed is

When Acetone Reacts With Bleaching Powder The Compound Formed Is Chemistry Question

When acetone reacts with bleaching powder, the compound formed is

Options

(a) CCl₄
(b) CHCl₃
(c) CH₃CHO
(d) CH₃COOH

Correct Answer:

CHCl₃

Explanation:

It involves two steps: CaOCl₂(Bleaching powder) + H₂O → Ca(OH)₂ + Cl₂ . (i)Chlorination of acetone to form trichloroacetone. CH₃COCH₃ + 3Cl₂ → CCl₃COCH₃ + 3HCl. (ii) Trichloroacetone is hydrolysed by Ca(OH)₂ present in bleaching powder to give chloroform. 2CCl₃COCH₃ + Ca(OH)₂ → 2CHCl₃(Chloroform) + (CH₃COO)₂Ca(Calcium acetate).

Related Questions:

  1. The correct order of electron affinity is
  2. The basic character of the transition metal monoxides follows the order.
  3. MnO₂ and H₂O added to Nacl, the greenish-yellow gas liberate is
  4. KCN reacts readily to give a cyanide with
  5. The correct order of the decreasing ionic radii among the following isoelectronic

Topics: Haloalkenes and Haloarenes (78)
Subject: Chemistry (2512)

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