In which of the following conditions a chemical reaction can not occur

In Which Of The Following Conditions A Chemical Reaction Can Chemistry Question

In which of the following conditions a chemical reaction can not occur

Options

(a) ΔH and ΔS increase and TΔS > ΔH
(b) ΔH and ΔS decrease and ΔH > TΔS
(c) ΔH increases and ΔS increases
(d) ΔH decreases and ΔS increases

Correct Answer:

ΔH increases and ΔS increases

Explanation:

(i)When ΔH and ΔS increase, then , if TΔS > ΔH the reaction is spontaneous.
Therefore ΔG = ΔH – TΔS = -ve.
(ii)When ΔH and ΔS decrease,then if ΔH > TΔS. This makes ΔG is -ve and process is spontaneous.
(iii) If , ΔH increases and ΔS decreases, then ΔG is +ve and process is non-spontaneous.
(iv) If ΔH decrease and ΔS increases, then ΔG is -ve and process is spontaneous.

Related Questions:

  1. In SN2 reaction the sequence of bond breaking and bond formation is as follows
  2. Which one of the following forms with an excess of CN⁻ (cyanide) a complex
  3. CCl₄ and freons
  4. Which one of the following statements about halogens is correct
  5. Which one of the following statements concerning lanthanides elements is false

Topics: Thermodynamics (179)
Subject: Chemistry (2512)

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