Which of the following reaction(s) can be used for the preparation of alkyl halides?

Which Of The Following Reactions Can Be Used For The Chemistry QuestionWhich Of The Following Reactions Can Be Used For The Chemistry Question

Which of the following reaction(s) can be used for the preparation of alkyl halides?
anh.ZnCl₂
(I)CH₃CH₂OH + HCl →
(II)CH₃CH₂OH + HCl →
(III)(CH₃)₃COH + HCl →
(IV)(CH₃)₂CHOH + HCl →

Options

(a) (I) and (II) only
(b) (IV) only
(c) (III) and (IV) only
(d) (I), (III) and (IV) only

Correct Answer:

(I), (III) and (IV) only

Explanation:

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  • In 1 and 4 due to presence of Lucas reagent alcohols gives alkyl halides and in 3 one it. Follows sn1 reaction

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