Heat of combustion ΔH for C(s) , H₂(g)and CH₄(g) are -94, -68 and -213 kcal/mol.

Heat of combustion ΔH for C(s) , H₂(g)and CH₄(g) are -94, -68 and -213 kcal/mol. Then ΔH for C(s) + 2H₂(g) → CH₄(g)is

Options

(a) -17 kcal
(b) -111kcal
(c) -170 kcal
(d) -85 kcal

Correct Answer:

-17 kcal

Explanation:

(i) C(s) + O₂ = CO₂ ; ΔH(i) = -94 kcal/mol,
(ii) 2H₂ + O₂ = 2H₂O ; ΔH(ii) = -68 x 2 kcal/mol,
(iii) CH₄ + 2O₂ = CO₂ + 2H₂O ; ΔH(iii) = -213 kcal/mol,
(iv) C(s) + 2H₂(g) = CH₄(g) ; ΔH(iv) = ?,
By applying Hess’s law we can compute ΔH(iv), (i) + (ii) – (iii), we have
C + O₂ + 2H₂ + O₂ – CH₄ – 2O₂ = CO₂ + 2H₂ O – CO₂ – 2H₂ O,
C+ 2H₂ = CH₄,
Therefore ΔH(iv) = ΔH(i) + ΔH(ii) – ΔH(iii) = (-94 – 68 x 2 + 213 ) kcal = -17 kcal.

admin:

Related Questions

  1. In the photo-electron emission,the energy of the emitted electron is
  2. The nitration (using nitration mixture) of aniline gives
  3. What is formed when nitrobenzene is reduced using zinc and alkali
  4. Atoms or ions missing from the normal lattice point creating a vacancy is due to
  5. The Formation of the oxide ion, O²⁻ from oxygen atom requires first an exothermic