Aniline is treated with a mixture of sodium nitrite and hypophosphorus acid, the product formed is
Options
(a) aniline diazonium hypophosphate
(b) benzene
(c) anilinium hypophosphite
(d) aniline diazonium hypophosphite
Correct Answer:
benzene
Explanation:
H₃PO₂ serves both as an acid as well as a reducing agent. The diazonium salt initially formed is reduced to give benzene. C₆H₅NH₂ → C₆H₅N₂⁺ HPO₂⁻ → C₆H₆ + N₂ .